Formation of a nanocrystalline layer on the surface of stone wool fibers

摘要

In the present paper, we report a simple approach for creating a nanocrystalline layer on the surface of stone wool fibers (SWFs) with a basalt-like composition. The approach is based on a preoxidation process of the SWFs in atmospheric air at a temperature around the glass transition temperature () for various durations. During preoxidation, the network-modifying ions diffuse from the interior toward the surface of SWFs and react with oxygen on the surface to form oxides. This diffusion process is accompanied by an inward diffusion of electron holes via the oxidation process of Fe to Fe. It is found that the diffusion of Mg is dominant in the overall diffusion process. The main phase of the nanocrystalline layer is identified to be periclase (MgO) crystals. The thickness of the nanocrystalline layer can be varied by adjusting the temperature and the duration of preoxidation. The nanocrystalline layer plays a significant role in enhancing the high-temperature stability of the SWFs.